Maleficent is a new character in Super Smash Bros. Crossover and a major antagonist during the Time Eater Arc. She, along with Jafar, were recruited by Ganondorf to help him seize control of the cannibal virus. Maleficent is seen, albeit in a cloak, warning Frieza and Orochimaru that failure is not an option. After Frieza and Orochimaru leave, Maleficent and Jafar reveal themselves and prepare to seize control of the cannibal virus and Gigadark Bowser.
- Maleficent, Jafar, Princess Daisy, and Time Eater are the only new characters to debut during the Time Eater Arc.
- Maleficent and Jafar are the only Disney characters in Super Smash Bros. Crossover.